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Aza analog of aminoxide
Let $\ce{Me=CH3}$. $\ce{Me3N+O-}$ (TMAO) is perfectly stable, no rearrangement to $\ce{Me2NOMe}$ (methoxyamine) occurs. What about $\ce{Me3N+N^-Me}$? $\ce{N-}$ moieties are much more unwilling to f...
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Aza analog of aminoxide
https://chemistry.stackexchange.com/questions/190556/aza-analog-of-aminoxide
Let $\ce{Me=CH3}$. $\ce{Me3N+O-}$ (TMAO) is perfectly stable, no rearrangement to $\ce{Me2NOMe}$ (methoxyamine) occurs. What about $\ce{Me3N+N^-Me}$? $\ce{N-}$ moieties are much more unwilling to f...
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Aza analog of aminoxide
Let $\ce{Me=CH3}$. $\ce{Me3N+O-}$ (TMAO) is perfectly stable, no rearrangement to $\ce{Me2NOMe}$ (methoxyamine) occurs. What about $\ce{Me3N+N^-Me}$? $\ce{N-}$ moieties are much more unwilling to f...
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